Ruthenium-Catalyzed ortho Alkenylation of Aromatics with Alkenes at Room Temperature with Hydrogen Evolution

Manikandan, Rajendran; Madasamy, Padmaja; JAYAKANNAN, MANICKAM

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dc.contributor.author	Manikandan, Rajendran	en_US
dc.contributor.author	Madasamy, Padmaja	en_US
dc.contributor.author	JAYAKANNAN, MANICKAM	en_US
dc.date.accessioned	2019-04-29T10:15:50Z
dc.date.available	2019-04-29T10:15:50Z
dc.date.issued	2016-01	en_US
dc.identifier.citation	ACS Catalysis, 6 (1), 230-234.	en_US
dc.identifier.issn	2155-5435	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2717
dc.identifier.uri	https://doi.org/10.1021/acscatal.5b02218	en_US
dc.description.abstract	A ruthenium-catalyzed oxidant-free highly regioselective ortho alkenylation of substituted aromatics such as aromatic amides, aromatic ketoximes, and anilides with alkenes in the presence of AgSbF6 and acetic acid in ClCH2CH2Cl at room temperature is described. The alkenylation reaction provides ortho alkenylated aromatics along with evolution of H2 gas. In the reaction, no oxidant was used, and the whole catalytic reaction has occurred without changing the oxidation state of the metal.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Ruthenium-Catalyzed	en_US
dc.subject	Alkenylation	en_US
dc.subject	Room Temperature	en_US
dc.subject	Hydrogen Evolution	en_US
dc.subject	Ambient temperature	en_US
dc.subject	C?H bond activation	en_US
dc.subject	Hydrogen evolution	en_US
dc.subject	Oxidant free	en_US
dc.subject	Ruthenium catalysis	en_US
dc.subject	2016	en_US
dc.title	Ruthenium-Catalyzed ortho Alkenylation of Aromatics with Alkenes at Room Temperature with Hydrogen Evolution	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	ACS Catalysis	en_US
dc.publication.originofpublisher	Foreign	en_US