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Modulation of Electrical and Thermal Conductivity in Metal-Organic Framework by Conducting Polymer

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dc.contributor.advisor BALLAV, NIRMALYA en_US
dc.contributor.author JADHAV, ASHWINI en_US
dc.date.accessioned 2019-05-07T08:48:37Z
dc.date.available 2019-05-07T08:48:37Z
dc.date.issued 2019-04 en_US
dc.identifier.uri http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2924
dc.description.abstract Metal-Organic Frameworks (MOFs) are well explored candidates in numerous fields such as gas storage, separation, sensing and more, however, most of them are intrinsically insulating in nature, due to which they lag behind in the domain of energy storage devices. Herein, we have assembled polypyrrole chains inside the nanochannels of a Zr-based framework (UiO-66) leading to a million fold electrical conductivity enhancement with a value of ~10-2 S/cm for UiO-66_PPy, at the minimal cost of porosity loss. Notably, at the same time, thermal conductivity increment in the nanocomposite is not huge, which is usually unavoidable where electrical conductivity and thermal conductivity cooperatively reforms. The nanocomposite was then tested for supercapacitor performance and revealed a value of 130mF/cm2 at current density of 0.2 mA/cm2 with almost 100% retention of the value after 10k cycles. en_US
dc.language.iso en en_US
dc.subject 2019
dc.subject Chemistry en_US
dc.title Modulation of Electrical and Thermal Conductivity in Metal-Organic Framework by Conducting Polymer en_US
dc.type Thesis en_US
dc.type.degree BS-MS en_US
dc.contributor.department Dept. of Chemistry en_US
dc.contributor.registration 20131118 en_US


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  • MS THESES [1705]
    Thesis submitted to IISER Pune in partial fulfilment of the requirements for the BS-MS Dual Degree Programme/MSc. Programme/MS-Exit Programme

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