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Embedding S=1/2 Kagome-like Lattice in Reduced Graphene Oxide

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dc.contributor.author GUPTA, KRITI en_US
dc.contributor.author JHA, PLAWAN KUMAR en_US
dc.contributor.author Dadwal, Arun en_US
dc.contributor.author Debnath, Anil K. en_US
dc.contributor.author JAISWAL, ISHAN en_US
dc.contributor.author RANA, SHAMMI en_US
dc.contributor.author Joy, Pattayil A. en_US
dc.contributor.author BALLAV, NIRMALYA en_US
dc.date.accessioned 2019-06-26T04:00:26Z
dc.date.available 2019-06-26T04:00:26Z
dc.date.issued 2019-05 en_US
dc.identifier.citation Journal of Physical Chemistry Letters, 10(11), 2663-2668. en_US
dc.identifier.issn 1948-7185 en_US
dc.identifier.uri http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3136
dc.identifier.uri https://doi.org/10.1021/acs.jpclett.9b00839 en_US
dc.description.abstract An elegant platform to explore frustrated magnetism is the kagome spin lattice. In this work, clinoatacamite, a naturally occurring S = 1/2 kagome-like antiferromagnetic insulator, is synthesized in water at ambient pressure for the first time from a cuprous chloride (CuCl) precursor whereby Cu(I) was spontaneously oxidized to Cu(II) in the form of clinoatacamite [Cu2(OH)3Cl] with a simultaneous reduction of graphene oxide (GO) to reduced graphene oxide (rGO) in one pot. A stable nanocomposite of phase-pure clinoatacamite nanocrystals embedded in the rGO matrix was isolated. The clinoatacamite–rGO nanocomposite was determined to be magnetically active with a markedly enhanced coercive field of ∼2500 Oe at 5 K as well as electronically active with a conductivity value of ∼200 S·m–1 at 300 K. Our results illustrate an avenue of combining exotic magnetic and electronic lattices without impeding their individual characteristics and synergistically generating a new class of magnetic semiconductors. en_US
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.subject Coercivity Enhancement en_US
dc.subject Antiferromagnet en_US
dc.subject Order en_US
dc.subject TOC-JUN-2019 en_US
dc.subject 2019 en_US
dc.title Embedding S=1/2 Kagome-like Lattice in Reduced Graphene Oxide en_US
dc.type Article en_US
dc.contributor.department Dept. of Chemistry en_US
dc.identifier.sourcetitle Journal of Physical Chemistry Letters en_US
dc.publication.originofpublisher Foreign en_US


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