A naphthalene-fused dimer of an anti-aromatic expanded isophlorin

Kgerler, Paul; REDDY, BADDIGAM KIRAN; Rawson, Jeff; ANAND, V. G.; GADEKAR, SANTOSH C.

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dc.contributor.author	REDDY, BADDIGAM KIRAN	en_US
dc.contributor.author	Rawson, Jeff	en_US
dc.contributor.author	GADEKAR, SANTOSH C.	en_US
dc.contributor.author	Kgerler, Paul	en_US
dc.contributor.author	ANAND, V. G.	en_US
dc.date.accessioned	2019-07-01T05:32:45Z
dc.date.available	2019-07-01T05:32:45Z
dc.date.issued	2017-06	en_US
dc.identifier.citation	Chemical Communications, 53(58), 8211-8214.	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3183
dc.identifier.uri	https://doi.org/10.1039/C7CC04050D	en_US
dc.description.abstract	We report the first synthesis of a covalent expanded isophlorin dimer from two 24-π doubly S-confused sapphyrin-like pentathiaisophlorins. It exhibits marginal peripheral aromaticity rather than strong global diatropicity or paratropicity and weak intermacrocycle electronic communication. Quantum chemical methods discern that cross-conjugation is responsible for these unusual electronic features.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Naphthalene-fused dimer	en_US
dc.subject	Isophlorin	en_US
dc.subject	Aromatic macrocycles	en_US
dc.subject	Two-electron oxidation	en_US
dc.subject	NMR spectroscopic	en_US
dc.subject	Covalent dimer can exist	en_US
dc.subject	2017	en_US
dc.title	A naphthalene-fused dimer of an anti-aromatic expanded isophlorin	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US