Transition-metal-free regioselective thiocyanation of phenols, anilines and heterocycles

KHOPADE, TUSHAR M.; BHAT, RAMAKRISHNA G.; Mete, Trimbak B.

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dc.contributor.author	Mete, Trimbak B.	en_US
dc.contributor.author	KHOPADE, TUSHAR M.	en_US
dc.contributor.author	BHAT, RAMAKRISHNA G.	en_US
dc.date.accessioned	2019-07-01T05:32:46Z
dc.date.available	2019-07-01T05:32:46Z
dc.date.issued	2017-02	en_US
dc.identifier.citation	Tetrahedron Letters, 58(5), 415-418.	en_US
dc.identifier.issn	0040-4039	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3197
dc.identifier.uri	https://doi.org/10.1016/j.tetlet.2016.12.043	en_US
dc.description.abstract	An expedient direct and regioselective thiocyanation of phenols, anilines and heterocycles is described. Transformation is realized via the direct CH functionalization under transition metal free conditions at ambient temperature in excellent yields. Method proved to be monoselective and variety of functional groups tolerated the reaction conditions. The practicality of the protocol is demonstrated in gram scale synthesis of a precursor of PPAR δ agonist in excellent yield.	en_US
dc.language.iso	en	en_US
dc.publisher	Elsevier B.V.	en_US
dc.subject	Transition metal free protocol	en_US
dc.subject	Radical pathway	en_US
dc.subject	Thiocyanation	en_US
dc.subject	Transition-metal-free	en_US
dc.subject	Persulphate	en_US
dc.subject	Radical cation	en_US
dc.subject	Radical scavenger	en_US
dc.subject	2017	en_US
dc.title	Transition-metal-free regioselective thiocyanation of phenols, anilines and heterocycles	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Tetrahedron Letters	en_US
dc.publication.originofpublisher	Foreign	en_US