NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity

Barman, Milan Kr.; Chandrasekhar, Vedapalli; Yildiz, Cem B.; Dhara, Debabrata; Carola, Schulzke; Chrysochos, Nicolas; BOOMISHANKAR, RAMAMOORTHY; VIJAYAKANTH, THANGAVEL; Jana, Anukul; Naik, Khevath Praveen Kumar

DR Home
→
PUBLICATIONS & PATENTS
→
JOURNAL ARTICLES
→
View Item

NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity

Dhara, Debabrata; VIJAYAKANTH, THANGAVEL; Barman, Milan Kr.; Naik, Khevath Praveen Kumar; Chrysochos, Nicolas; Yildiz, Cem B.; BOOMISHANKAR, RAMAMOORTHY; Carola, Schulzke; Chandrasekhar, Vedapalli; Jana, Anukul

URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3201 https://doi.org/10.1039/C7CC03912C Date: 2017-07

Abstract:

A facile, straightforward synthesis of N-heterocyclic carbene (NHC)-stabilized 1-hydrosilaimine starting from a silicon(IV)-precursor is reported. It has been employed for the addition of an O-H bond of water under ambient conditions without any additional catalyst.

Show full item record