Visible-Light-Triggered Uncaging of Carbonyl Sulfide for Hydrogen Sulfide (H2S) Release

CHAKRAPANI, HARINATH; Nair, Mrutyunjay; Saini, Deepak Kumar; SHARMA, AJAY KUMAR; Gupta, Kavya; Chauhan, Preeti

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dc.contributor.author	SHARMA, AJAY KUMAR	en_US
dc.contributor.author	Nair, Mrutyunjay	en_US
dc.contributor.author	Chauhan, Preeti	en_US
dc.contributor.author	Gupta, Kavya	en_US
dc.contributor.author	Saini, Deepak Kumar	en_US
dc.contributor.author	CHAKRAPANI, HARINATH	en_US
dc.date.accessioned	2019-07-01T05:33:18Z
dc.date.available	2019-07-01T05:33:18Z
dc.date.issued	2017-09	en_US
dc.identifier.citation	Organic Letters, 19 (18), 4822-4825.	en_US
dc.identifier.issn	1523-7060	en_US
dc.identifier.issn	1523-7052	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3212
dc.identifier.uri	https://doi.org/10.1021/acs.orglett.7b02259	en_US
dc.description.abstract	Generation of hydrogen sulfide (H2S) is challenging and few methods are capable of localized delivery of this gas. Here, a boron dipyrromethene-based carbamothioate (BDP-H2S) that is uncaged by visible light of 470 nm to generate carbonyl sulfide (COS), which is rapidly hydrolyzed to H2S in the presence of carbonic anhydrase, a widely prevalent enzyme, is reported.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Visible-Light-Triggered	en_US
dc.subject	Uncaging of Carbonyl	en_US
dc.subject	Hydrogen Sulfide	en_US
dc.subject	Carbamothioate	en_US
dc.subject	Prevalent enzyme	en_US
dc.subject	2017	en_US
dc.title	Visible-Light-Triggered Uncaging of Carbonyl Sulfide for Hydrogen Sulfide (H2S) Release	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Organic Letters	en_US
dc.publication.originofpublisher	Foreign	en_US