Solvent-controlled selective synthesis of biphenols and quinones via oxidative coupling of phenols

dc.contributor.author	More, Nagnath Yadav	en_US
dc.contributor.author	JEGANMOHAN, MASILAMANI	en_US
dc.date.accessioned	2019-07-01T05:34:35Z
dc.date.available	2019-07-01T05:34:35Z
dc.date.issued	2017-08	en_US
dc.identifier.citation	Chemical Communications, 53(69), 9616-9619.	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3256
dc.identifier.uri	https://doi.org/10.1039/C7CC04829G	en_US
dc.description.abstract	A regioselective synthesis of unsymmetrical and symmetrical biphenols and binaphthols via oxidative coupling of phenols or naphthols in the presence of K2S2O8 in CF3COOH under ambient conditions is described. Interestingly, the 1 : 1 ratio of H2O and CH3CN solvent mixtures at 80 °C instead of CF3COOH provided substituted unsymmetrical quinones. A gram-scale synthesis of biphenols and binaphthols was demonstrated.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Solvent-controlled	en_US
dc.subject	Oxidative coupling of phenols	en_US
dc.subject	Ambient conditions	en_US
dc.subject	Para-para coupling products	en_US
dc.subject	2017	en_US
dc.title	Solvent-controlled selective synthesis of biphenols and quinones via oxidative coupling of phenols	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US