Strikingly diverse reactivity of structurally identical silylene and stannylene

DASGUPTA, RAJARSHI; KHAN, SHABANA; Sen, Sakya S.; PARVIN, NASRINA; PAL, SHIV

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dc.contributor.author	PARVIN, NASRINA	en_US
dc.contributor.author	DASGUPTA, RAJARSHI	en_US
dc.contributor.author	PAL, SHIV	en_US
dc.contributor.author	Sen, Sakya S.	en_US
dc.contributor.author	KHAN, SHABANA	en_US
dc.date.accessioned	2019-07-01T05:35:12Z
dc.date.available	2019-07-01T05:35:12Z
dc.date.issued	2017-04	en_US
dc.identifier.citation	Dalton Transactions, 46(20), 6528-6532.	en_US
dc.identifier.issn	1477-9226	en_US
dc.identifier.issn	1477-9234	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3262
dc.identifier.uri	https://doi.org/10.1039/C7DT01055A	en_US
dc.description.abstract	The reactivity of structurally identical silylene and stannylene [PhC(NtBu)2EN(SiMe3)2] (E = Si (1) and Sn (2)) towards coinage metals has been explored. While 1 has the propensity to form an adduct with coinage metals (4 and 5), 2 undergoes a ligand exchange reaction with copper halides and silver triflate leading to PhC(NtBu)2SnX (X = Br (6), Cl (7), and OSO2CF3 (8)) with concomitant formation of [M{N(SiMe3)2}] (M = Cu, Ag). However, with AgSbF6 both 1 and 2 led to ion pairs, 9+-SbF6-and 10+-SbF6- displaying weaker Ag?-F interactions in the latter.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Strikingly diverse	en_US
dc.subject	Stannylene	en_US
dc.subject	Functionalized stannylenes	en_US
dc.subject	Single crystals	en_US
dc.subject	2017	en_US
dc.title	Strikingly diverse reactivity of structurally identical silylene and stannylene	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Dalton Transactions	en_US
dc.publication.originofpublisher	Foreign	en_US