Direct coordination of a germanium(II) dicationic center to transition metals

dc.contributor.author	Rauta, Ravindra K.	en_US
dc.contributor.author	MAJUMDAR, MOUMITA	en_US
dc.date.accessioned	2019-07-01T05:35:13Z
dc.date.available	2019-07-01T05:35:13Z
dc.date.issued	2017-01	en_US
dc.identifier.citation	Chemical Communications, 53(9), 1467-1469 .	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3268
dc.identifier.uri	https://doi.org/10.1039/C6CC09525A	en_US
dc.description.abstract	The germanium(II) center of dicationic compound 1 donates an electron pair to transition metal Ag(I) and Au(I) cations, leading to complexes 2 and 3 respectively. Complex 3 is stabilized by [Ge:]2+→Au(I) σ-donation and π-back donation from filled d-orbitals of Au(I) to the two sets of p-orbitals available on Ge(II) centers.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Direct coordination	en_US
dc.subject	Dicationic center	en_US
dc.subject	Transition metals	en_US
dc.subject	Azamacrocycles	en_US
dc.subject	2017	en_US
dc.title	Direct coordination of a germanium(II) dicationic center to transition metals	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US