C(sp3)–F, C(sp2)–F and C(sp3)–H bond activation at silicon(ii) centers

dc.contributor.author	Swamy, V. S. V. S. N.	en_US
dc.contributor.author	PARVIN, NASRINA	en_US
dc.contributor.author	Raj, K. Vipin	en_US
dc.contributor.author	Vanka, Kumar	en_US
dc.contributor.author	Sen, Sakya S.	en_US
dc.date.accessioned	2019-07-01T05:35:43Z
dc.date.available	2019-07-01T05:35:43Z
dc.date.issued	2017-08	en_US
dc.identifier.citation	Chemical Communications, 53(71),9850-9853.	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3286
dc.identifier.uri	https://doi.org/10.1039/C7CC05145J	en_US
dc.description.abstract	Silylene [PhC(NtBu)2SiN(SiMe3)2] (1) cleaves the C(sp3)–H and C–F bonds of acetophenone and 1,1,1-trifluoroacetophenone, respectively, under mild conditions. The reaction is initiated via a nucleophilic attack from the oxygen to the silicon atom followed by C–F/H bond cleavage. The scope of C–F bond activation has further been extended with C6F6 and C6F5CF3.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Silylene	en_US
dc.subject	Nucleophilic attack	en_US
dc.subject	High activation barrier	en_US
dc.subject	Defluorination	en_US
dc.subject	2017	en_US
dc.title	C(sp3)–F, C(sp2)–F and C(sp3)–H bond activation at silicon(ii) centers	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US