Ultra‐microporous Metal–Organic Framework Built from Rigid Linkers Showing Structural Flexibility Resulting in a Marked Change in Carbon Dioxide Capacity

VAIDHYANATHAN, RAMANATHAN; Chakraborty, Debanjan; Banerjee, Aparna

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dc.contributor.author	Banerjee, Aparna	en_US
dc.contributor.author	Chakraborty, Debanjan	en_US
dc.contributor.author	VAIDHYANATHAN, RAMANATHAN	en_US
dc.date.accessioned	2019-07-01T05:36:15Z
dc.date.available	2019-07-01T05:36:15Z
dc.date.issued	2017-05	en_US
dc.identifier.citation	European Journal of Inorganic Chemistry, 2017(18), 2464-2468.	en_US
dc.identifier.issn	1434-1948	en_US
dc.identifier.issn	1099-0682	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3313
dc.identifier.uri	https://doi.org/10.1002/ejic.201700107	en_US
dc.description.abstract	An ultra‐microporous CoHAtzOx (HAtz = aminotriazole, Ox = oxalate) metal–organic framework with a 3D framework showing guest‐dependent reversible structural transformations was studied. The flexibility was found to arise from buckling of the rigid Co–Ox and Co–HAtz chains, which yields a desolvated structure with a 78 % lower void volume and significantly lower CO2 capacity.	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley	en_US
dc.subject	Microporous materials	en_US
dc.subject	Built from Rigid	en_US
dc.subject	Linkers Showing	en_US
dc.subject	Structural Flexibility	en_US
dc.subject	Carbon Dioxide Capacity	en_US
dc.subject	2017	en_US
dc.title	Ultra‐microporous Metal–Organic Framework Built from Rigid Linkers Showing Structural Flexibility Resulting in a Marked Change in Carbon Dioxide Capacity	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	European Journal of Inorganic Chemistry	en_US
dc.publication.originofpublisher	Foreign	en_US