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The molecular spin state of NiII porphyrin, supported on a ferromagnetic Co surface, can be reversibly switched between spin‐off (S=0) and spin‐on (S=1) states upon coordination and decoordination of the gaseous ligand NH3, respectively (see picture). This finding clearly indicates the possible use of the system as a single‐molecule‐based magnetochemical sensor and in spintronics.

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dc.contributor.author GOPALAKRISHNA, TULLIMILLI Y. en_US
dc.contributor.author REDDY, J. SREEDHAR en_US
dc.contributor.author ANAND, V. G. en_US
dc.date.accessioned 2019-07-23T11:08:15Z
dc.date.available 2019-07-23T11:08:15Z
dc.date.issued 2013-02 en_US
dc.identifier.citation Angewandte Chemie, 52(6), 1763-1767. en_US
dc.identifier.issn 1433-7851 en_US
dc.identifier.issn 1521-3773 en_US
dc.identifier.uri http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3596
dc.identifier.uri https://doi.org/10.1002/anie.201207987 en_US
dc.description.abstract Count against: Stable and planar antiaromatic, expanded vinylogous isophlorins encourage chalcogen–fluorine noncovalent interactions. The wide cavity of the macrocycle accommodates covalently bound fluorine substituents, thus leading to multiple nonbonding interactions en_US
dc.language.iso en en_US
dc.publisher Wiley en_US
dc.subject Antiaromaticity en_US
dc.subject Conjugation en_US
dc.subject Macrocycles en_US
dc.subject Noncovalent interactions en_US
dc.subject ? interactions en_US
dc.subject 2013 en_US
dc.title The molecular spin state of NiII porphyrin, supported on a ferromagnetic Co surface, can be reversibly switched between spin‐off (S=0) and spin‐on (S=1) states upon coordination and decoordination of the gaseous ligand NH3, respectively (see picture). This finding clearly indicates the possible use of the system as a single‐molecule‐based magnetochemical sensor and in spintronics. en_US
dc.type Article en_US
dc.contributor.department Dept. of Chemistry en_US
dc.identifier.sourcetitle Angewandte Chemie en_US
dc.publication.originofpublisher Foreign en_US


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