The syntheses and photophysical properties of PNP-based Au(i) complexes with strong intramolecular Au center dot center dot center dot Au interactions

DASGUPTA, RAJARSHI; KHAN, SHABANA; KUMAR, NANDHA; GHOSH, MOUSHAKHI; KATHEWAD, NEHA; PAL, SHIV

DR Home
→
PUBLICATIONS & PATENTS
→
JOURNAL ARTICLES
→
View Item

dc.contributor.author	KATHEWAD, NEHA	en_US
dc.contributor.author	KUMAR, NANDHA	en_US
dc.contributor.author	DASGUPTA, RAJARSHI	en_US
dc.contributor.author	GHOSH, MOUSHAKHI	en_US
dc.contributor.author	PAL, SHIV	en_US
dc.contributor.author	KHAN, SHABANA	en_US
dc.date.accessioned	2019-07-24T07:05:52Z
dc.date.available	2019-07-24T07:05:52Z
dc.date.issued	2019-02	en_US
dc.identifier.citation	Dalton Transactions, 48(21), 7274-7280.	en_US
dc.identifier.issn	1477-9226	en_US
dc.identifier.issn	1477-9234	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3774
dc.identifier.uri	https://doi.org/10.1039/c8dt04471f	en_US
dc.description.abstract	Herein we report the syntheses, X-ray structures and photophysical studies of the dinuclear dimeric gold(i) complexes [ClAu(C6H5N)(PPh2)(2)](2) (1), [Au(C6H5N)(PPh2)(2)](2)[SbF6](2) (2) and [Au(2,6-Me2C6H3N)(PPh2)(2)](2)[SbF6](2) (4). We have used ligands with different substituents to see the effect of the substituents on the photophysical properties. All these complexes feature strong intramolecular AuAu interactions (2.7987-3.0056 angstrom) and were found to exhibit excellent luminescence properties with high quantum yields as well as different colors of emission.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Chemistry	en_US
dc.subject	2019	en_US
dc.title	The syntheses and photophysical properties of PNP-based Au(i) complexes with strong intramolecular Au center dot center dot center dot Au interactions	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Dalton Transactions	en_US
dc.publication.originofpublisher	Foreign	en_US