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Perspective on the Interfacial Reduction Reaction

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dc.contributor.author RANA, SHAMMI en_US
dc.contributor.author SINDHU, POOJA en_US
dc.contributor.author BALLAV, NIRMALYA en_US
dc.date.accessioned 2019-08-26T06:52:59Z
dc.date.available 2019-08-26T06:52:59Z
dc.date.issued 2019-07 en_US
dc.identifier.citation Langmuir, 35(30), 9647-9659. en_US
dc.identifier.issn 0743-7463 en_US
dc.identifier.uri http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3806
dc.identifier.uri https://doi.org/10.1021/acs.langmuir.9b01250 en_US
dc.description.abstract Chemical reactions involving oxidation and reduction processes at interfaces may vary from those in conventional liquid-phase or solid-phase reactions and could influence the overall outcome. This article primarily features a study on metal–ligand coordination at the solid–liquid interface. Of particular mention is the spontaneous reduction of Cu(II) to Cu(I) at a solid–liquid interface without the need of any extraneous reducing agent, unlike in the liquid-phase reaction whereby no reduction of Cu(II) to Cu(I) took place. As a consequence of the interfacial reduction reaction (IRR), thin films of Cu-TCNQ (tetracyanoquinodimethane) and Cu-HCF (hexacyanoferrate) were successfully deposited onto a thiol-functionalized Au substrate via a layer-by-layer (LbL) method. IRR is anticipated to be useful in generating new functional and stimuli-responsive materials, which are otherwise difficult to achieve via conventional liquid-phase reactions. en_US
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.subject Metal-Organic Frameworks en_US
dc.subject Self-Assembled Monolayers en_US
dc.subject Thin-Films en_US
dc.subject Prussian Blue en_US
dc.subject Electrical-Conductivity en_US
dc.subject Coordination Chemistry en_US
dc.subject Growth en_US
dc.subject Surfaces en_US
dc.subject Gold en_US
dc.subject Site en_US
dc.subject TOC-AUG-2019 en_US
dc.subject 2019 en_US
dc.title Perspective on the Interfacial Reduction Reaction en_US
dc.type Article en_US
dc.contributor.department Dept. of Chemistry en_US
dc.identifier.sourcetitle Langmuir en_US
dc.publication.originofpublisher Foreign en_US


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