Chalcogens, sulfur and selenium, play essential biological roles as components of functional groups in biomolecules, and are closely involved in redox reactions. Hydrogen sulfide (H2S) is involved in various mammalian ...
Low-valent main-group compounds, possessing at least one lone pair and a vacant p-orbital, have emerged as strong contenders to transition metals due to the low-lying energy separation between their frontier molecular ...
C–H functionalization represents a transformative strategy in organic synthesis,
enabling the direct modification of carbon–hydrogen bonds into a wide range of functional
groups. This approach eliminates the need for ...
Plants grow in a highly dynamic and complex environment, where adaptability and plasticity are key factors for their survival and development. Mobile signals, whether short- or long-distance, play an essential role in ...
Matching sensory stimuli involves different decision processes such as detection and discrimination, along with holding the perceived information. Therefore, it provides a combined readout of sensory and cognitive fitness. ...
This first five chapters of this thesis are concerned with the study of some two-player combinatorial games on random premises. These chapter include 1. the k-jump normal and k-jump misere ` games on rooted Galton-Watson ...
Nucleic acids adopt diverse secondary and tertiary structures, which play critical roles in various biological processes beyond encoding genetic information. It is essential to modify nucleic acids with biophysical probes ...
Metazoan embryonic development relies on precise cellular and morphogenetic processes, which are highly-energy intensive. Mitochondria, the powerhouse of the cell, play vital roles in various such morphogenetic events for ...
Life is hypothesized to have originated in primordial or prebiotic soup, which is thought to have been a heterogenous mixture of various chemicals present on early Earth. However, even the simplest unicellular forms of ...
Malaria caused by the Plasmodium falciparum is driven by alterations in the infected RBC surface by recruiting antigens that can bind to the endothelial receptors (cytoadherence). The clonally variant multigene family of ...
The emergence of correlated phases in low-dimensional quantum materials presents a platform for discovering new physics and phenomenon. These emergent orders such as charge density wave (CDW), magnetism, superconductivity, ...
Organocatalysis has become one of the essential pillars of asymmetric catalysis, complementing enzyme and chiral metal catalysis. Over the last few decades, various carbon-carbon and carbon-hetero (C-C and C-X) bond-forming ...
Diazo compounds are highly valued in synthetic organic chemistry due to their broad reactivity and wide-ranging applications. They exhibit distinct reactivity towards metals as well as visible light. It is well known that ...
NHC/NHSi-ligated Transition Metal Complexes: Versatile Platforms for Catalysis and Small Molecule Activation
Sandeep Kaulage and Shabana Khan*
The chemistry of N-heterocyclic carbenes (NHCs) and N-heterocyclic silylene ...
Excessive accumulation of greenhouse gases such as methane (CH₄) and carbon
dioxide (CO₂) in the atmosphere is a major contributor to global environmental
challenges. An effective approach to mitigate this issue is to ...
The Membrane-associated Periodic Skeleton (MPS) is a critical cytoskeletal structure observed in diverse neuronal subtypes across multiple species. Since its identification in 2013, it has been demonstrated to be essential ...
Diazo compounds are highly versatile as well as valuable reagents whose reactivity can be fine-tuned through metal catalysis, photochemical activation, and radical pathways to enable divergent and selective synthetic ...
Nature has always been the underlying inspiration for various solar energy conversion technologies and among them, solar-to-chemical energy conversion in photosynthesis is considered to be the most elegant way to make ...
In recent years, algebraic quantum field theory (AQFT) and modular theory have provided significant insights into gravitational degrees of freedom. Notably, the works [1–3] demonstrate that the inclusion of gravitational ...
One of the goals of early universe cosmology is to understand the physics of inflation. Since we cannot visually access this epoch, we rely on indirect observations, e.g., measuring temperature correlations on the CMB. By ...