Transition-Metal-Free Addition Reaction for the Synthesis of 3-(Aminobenzylidene/aminoalkylidene)indolin-2-ones and Its Synthetic Applications

GNANAPRAKASAM, BOOPATHY; BISHT, GIRISH SINGH

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dc.contributor.author	BISHT, GIRISH SINGH	en_US
dc.contributor.author	GNANAPRAKASAM, BOOPATHY	en_US
dc.date.accessioned	2019-11-29T11:37:17Z
dc.date.available	2019-11-29T11:37:17Z
dc.date.issued	2019-09	en_US
dc.identifier.citation	Journal of Organic Chemistry, 84(21), 13516-13527.	en_US
dc.identifier.issn	1520-6904	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4198
dc.identifier.uri	https://doi.org/10.1021/acs.joc.9b01771	en_US
dc.description.abstract	A novel and efficient transition-metal-free approach for the exclusive synthesis of Z-3-(aminobenzylidene/aminoalkylidene)indolin-2-ones in high yield from 2-oxindole and aryl/alkyl nitrile in the presence of LiOtBu and 2,2?-bipyridine system is described. In addition, we disclosed a new approach towards the metal-free fluorination using selectfluor and the C?C bond cleavage using CuI and environmentally benign O2.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Beta-Dicarbonyl\|Compounds	en_US
dc.subject	One-Pot Synthesis	en_US
dc.subject	C Double-Bond	en_US
dc.subject	Heterocyclic Synthesis	en_US
dc.subject	Oxidative Cleavage	en_US
dc.subject	Coupling	en_US
dc.subject	TOC-NOV-2019	en_US
dc.subject	2019	en_US
dc.title	Transition-Metal-Free Addition Reaction for the Synthesis of 3-(Aminobenzylidene/aminoalkylidene)indolin-2-ones and Its Synthetic Applications	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Journal of Organic Chemistry	en_US
dc.publication.originofpublisher	Foreign	en_US