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Photochemical hydrogen evolution from water by a 1D-network of octahedral Ni6L8 cages

Photochemical hydrogen evolution from water by a 1D-network of octahedral Ni6L8 cages

KUMAR, KILAPARTHI SRAVAN; Mane, Vishwanath S.; YADAV, ASHOK; Kumbhar, Avinash S.; BOOMISHANKAR, RAMAMOORTHY
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4216
https://doi.org/10.1039/C9CC06286F
Date: 2019-10


Abstract:

A self-assembled M6L8 type cage-connected 1D-coordination network of formula {[Ni6(MeSi(3py)3)8Cl9(H2O)2]Cl3·16H2O}∞ (1) was obtained from a 3-pyridyl substituted silane ligand MeSi(3py)3. This complex shows significantly high performance for the electrocatalytic and photocatalytic hydrogen evolution reaction (HER) in water. A maximum turnover number (TON) of 2824 has been observed for photocatalytic HER after 69 h.

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