Photochemical hydrogen evolution from water by a 1D-network of octahedral Ni6L8 cages

YADAV, ASHOK; KUMAR, KILAPARTHI SRAVAN; Kumbhar, Avinash S.; Mane, Vishwanath S.; BOOMISHANKAR, RAMAMOORTHY

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dc.contributor.author	KUMAR, KILAPARTHI SRAVAN	en_US
dc.contributor.author	Mane, Vishwanath S.	en_US
dc.contributor.author	YADAV, ASHOK	en_US
dc.contributor.author	Kumbhar, Avinash S.	en_US
dc.contributor.author	BOOMISHANKAR, RAMAMOORTHY	en_US
dc.date.accessioned	2019-11-29T12:01:06Z
dc.date.available	2019-11-29T12:01:06Z
dc.date.issued	2019-10	en_US
dc.identifier.citation	Chemical Communications, 55(87), 13156-13159.	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4216
dc.identifier.uri	https://doi.org/10.1039/C9CC06286F	en_US
dc.description.abstract	A self-assembled M6L8 type cage-connected 1D-coordination network of formula {[Ni6(MeSi(3py)3)8Cl9(H2O)2]Cl3·16H2O}∞ (1) was obtained from a 3-pyridyl substituted silane ligand MeSi(3py)3. This complex shows significantly high performance for the electrocatalytic and photocatalytic hydrogen evolution reaction (HER) in water. A maximum turnover number (TON) of 2824 has been observed for photocatalytic HER after 69 h.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Metal-Organic Frameworks	en_US
dc.subject	Complexes	en_US
dc.subject	Nickel	en_US
dc.subject	Catalysts	en_US
dc.subject	Electrocatalyst	en_US
dc.subject	Generation	en_US
dc.subject	Challenges	en_US
dc.subject	TOC-NOV-2019	en_US
dc.subject	2019	en_US
dc.title	Photochemical hydrogen evolution from water by a 1D-network of octahedral Ni6L8 cages	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US