Silver‐Catalyzed Epoxidation of Aldehydes Using Donor‐/ Acceptor‐type Vinyl Diazosuccinimides to Access Spiro‐Pyrrolidinedioneoxiranes

BHAT, RAMAKRISHNA G.; LAHA, DEBASISH

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dc.contributor.author	LAHA, DEBASISH	en_US
dc.contributor.author	BHAT, RAMAKRISHNA G.	en_US
dc.date.accessioned	2020-04-30T05:43:37Z
dc.date.available	2020-04-30T05:43:37Z
dc.date.issued	2020-06	en_US
dc.identifier.citation	Asian Journal of Organic Chemistry, 9(6), 918-921.	en_US
dc.identifier.issn	2193-5815	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4562
dc.identifier.uri	https://doi.org/10.1002/ajoc.202000123	en_US
dc.description.abstract	A silver(I)‐catalyzed method to access spiro‐pyrrolidinedioneoxiranes has been developed. Silver hexafluoroantimonate was found to be an efficient catalyst for the epoxidation of aldehydes using donor‐/acceptor‐substituted vinyl diazosuccinimides as carbenoid precursors. The protocol has been found to be highly regio‐ and chemoselective, and works well with aromatic aldehydes containing electron‐withdrawing and ‐donating groups to afford spiro‐pyrrolidinedioneoxiranes with a broad substrate scope.	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley	en_US
dc.subject	Spiro-oxiranes	en_US
dc.subject	Diazo compounds	en_US
dc.subject	Silver	en_US
dc.subject	Carbenoids	en_US
dc.subject	Synthetic methods	en_US
dc.subject	TOC-APR-2020	en_US
dc.subject	2020	en_US
dc.subject	2020-APR-WEEK5	en_US
dc.title	Silver‐Catalyzed Epoxidation of Aldehydes Using Donor‐/ Acceptor‐type Vinyl Diazosuccinimides to Access Spiro‐Pyrrolidinedioneoxiranes	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Asian Journal of Organic Chemistry	en_US
dc.publication.originofpublisher	Foreign	en_US