Digital Repository

Zn7O2(RCOO)(10) Clusters and Nitro Aromatic Linkers in a Porous Metal-Organic Framework

Zn7O2(RCOO)(10) Clusters and Nitro Aromatic Linkers in a Porous Metal-Organic Framework

Iremonger, Simon S.; VAIDHYANATHAN, RAMANATHAN; Mah, Roger K.; Shimizu, George K. H.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5186
https://doi.org/10.1021/ic302127y
Date: 2013-03


Abstract:

A new metal–organic framework, CALF-22 comprising Zn7O2(COO)10 secondary building units and 2-nitro-1,4-benzenedicarboxylate, is reported. The porosity and gas adsorption of N2, H2, CO2, and CH4 are studied, and CALF-22 has a surface area in excess of 1000 m2/g. The stability of the larger zinc cluster and the effect of the nitro group on gas sorption are also studied.

Show full item record

Files in this item

Files Size Format View

There are no files associated with this item.

This item appears in the following Collection(s)

Search Repository


Advanced Search

Browse

My Account