Enhancing the carbon capture capacities of a rigid ultra-microporous MOF through gate-opening at low CO2 pressures assisted by swiveling oxalate pillars

VAIDHYANATHAN, RAMANATHAN; NASA, PARVEEN; BANERJEE, APARNA; NANDI, SHYAMAPADA

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dc.contributor.author	BANERJEE, APARNA	en_US
dc.contributor.author	NANDI, SHYAMAPADA	en_US
dc.contributor.author	NASA, PARVEEN	en_US
dc.contributor.author	VAIDHYANATHAN, RAMANATHAN	en_US
dc.date.accessioned	2020-10-26T10:55:29Z
dc.date.available	2020-10-26T10:55:29Z
dc.date.issued	2016-01	en_US
dc.identifier.citation	Chemical Communications, 52(9), 1851-1854.	en_US
dc.identifier.issn	359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5316
dc.identifier.uri	https://doi.org/10.1039/C5CC08172F	en_US
dc.description.abstract	Porosity enhancement assisted by an unusual gate opening has been realized in an exceptionally rigid ultra-microporous framework. The gate-opening has been attributed to the presence of symmetrically positioned Zn–O bonds of the Zn–oxalate units that facilitate subtle swiveling motion resulting in a drastic improvement (42%) in the CO2 capacity without compromising the CO2/N2 selectivity.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Metal-Organic-Frameworks	en_US
dc.subject	Gas-Adsorption	en_US
dc.subject	Separation	en_US
dc.subject	ZIF-8	en_US
dc.subject	Simulations	en_US
dc.subject	Dynamics	en_US
dc.subject	2016	en_US
dc.title	Enhancing the carbon capture capacities of a rigid ultra-microporous MOF through gate-opening at low CO2 pressures assisted by swiveling oxalate pillars	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US