The diverse reactivity of NOBF4 towards silylene, disilene, germylene and stannylene

KHAN, SHABANA; PARVIN, NASRINA; SEN, NILANJANA; Parameswaran, Pattiyil; Tothadi, Srinu; Muhasina, Puthan Veetil

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dc.contributor.author	PARVIN, NASRINA	en_US
dc.contributor.author	SEN, NILANJANA	en_US
dc.contributor.author	Muhasina, Puthan Veetil	en_US
dc.contributor.author	Tothadi, Srinu	en_US
dc.contributor.author	Parameswaran, Pattiyil	en_US
dc.contributor.author	KHAN, SHABANA	en_US
dc.date.accessioned	2021-05-13T11:49:23Z
dc.date.available	2021-05-13T11:49:23Z
dc.date.issued	2021-05	en_US
dc.identifier.citation	Chemical Communications, 57(41), 5008-5011.	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5867
dc.identifier.uri	https://doi.org/10.1039/d1cc01034d	en_US
dc.description.abstract	The reactivity of NOBF4 towards silylene, disilene, germylene, stannylenes has been described. Smooth syntheses of compounds of composition [PhC(NtBu)(2)E(= O -> BF3)N(SiMe3)(2), E = Si (3) and Ge (4)] were accomplished from the corresponding tetrylenes. An unusual heterocycle (10) featuring B, Sn, N, P, and O atoms was obtained from the reaction with a stannylene, while a 1,2-vicinal anti addition of fluoride was observed with a disilene (12).	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Chemistry	en_US
dc.subject	2021-MAY-WEEK2	en_US
dc.subject	TOC-MAY-2021	en_US
dc.subject	2021	en_US
dc.title	The diverse reactivity of NOBF4 towards silylene, disilene, germylene and stannylene	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US