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  • N-heterocyclic silylene stabilized monocordinated copper(i)-arene cationic complexes and their application in click chemistry 
    PARVIN, NASRINA; HOSSAIN, JABED; George, Anjana; Parameswaran, Pattiyil; KHAN, SHABANA (Royal Society of Chemistry, 2020-01)
    Herein for the first time we report monocoordinated cationic Cu(i) complexes with unsymmetrical arenes (toluene and m-xylene) [LCu(eta(3)-C7H8)](+)[SbF6](-) and [{LCu(eta(2)-Me2C6H4)}](+)[SbF6](-) [L = {PhC(NtBu)(2)SiN(S ...
  • N-Heterocyclic silylene/germylene ligands in Au(i) catalysis 
    PARVIN, NASRINA; MISHRA, BIJOYANANDA; George, Anjana; NERALKAR, MAHESH; HOSSAIN, JABED; Parameswaran, Pattiyil; HOTHA, SRINIVAS; KHAN, SHABANA (Royal Society of Chemistry, 2020-07)
    Cationic Au(I) complexes (2, 5 and 8) supported by N-heterocyclic carbene, silylene and germylene ligands were prepared and their potential as catalysts in glycosidation chemistry has been evaluated. Insights into the ...
  • Luminescent coinage metal complexes of carbenes 
    HOSSAIN, JABED; AKHTAR, RUKSANA; KHAN, SHABANA (Elsevier B.V., 2021-06)
    Recent years have witnessed a meteoric rise in the utilization of carbenes as ligands for the synthesis of coinage metal complexes due to their potential application in various fields. One of the very promising applications ...
  • Four-Coordinate Germylene and Stannylene and their Reactivity towards Se & Te 
    HOSSAIN, JABED; PARVIN, NASRINA; SHAH, BRIJ KUMAR; KHAN, SHABANA (Wiley, 2022-10)
    In this work, we have prepared a bulky ligand supported chlorogermylene (LGeCl) [L=C6H4-2-{C(Me)=NAr*}; Ar*=(2,6-bis(diphenylmethyl)-4-methylphenyl)] (2), chlorostannylene (LSnCl) (3), four-coordinate germylene (L2Ge) (4) ...
  • NHSi/NHGe-Supported Copper Halide and Pseudohalide Complexes: Synthesis and Application 
    HOSSAIN, JABED; Gopinath, Jishnu Sai; Tothadi, Srinu; Parameswaran, Pattiyil; KHAN, SHABANA (American Chemical Society, 2022-12)
    Herein, we have demonstrated the complexation reaction of silylene and germylene [PhC(NtBu)2EN(TMS)2; E = Si (A) and Ge (B)] with several copper(I) salts and further utilized them (1–6) as efficient catalysts in CuAAC ...

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