The development of sustainable methods for the synthesis of amines using commercially available/easy-to-synthesize catalysts under mild conditions is one of the current interests in catalysis. A method of amide-to-amine ...

In this work, we have reduced CO2 with HBpin to afford borylated methanol product selectively in ~99 % yield using Ce[N(SiMe3)2]3(THF)3 as a catalyst. This led to multigram scale isolation of methanol obtained from CO2 ...