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Reductive Cleavage of Carbon Monoxide by a Disilenide

MAJUMDAR, MOUMITA; Omlor, Isabell; Yildiz, Cem B.; Azizoglu, Akin; Huch, Volker; Scheschkewitz, David (Wiley, 2015-07)

The complete reductive cleavage of the triple bond in carbon monoxide was achieved using a lithium disilenide at room temperature. The CC‐coupled product can be regarded as a silanone dimer with pending alkyne and silirene ...
Phenylene-bridged cross-conjugated 1,2,3-trisilacyclopentadienes

Zhao, Hui; Klemmer, Lukas; Cowley, Michael J.; MAJUMDAR, MOUMITA; Huch, Volker; Zimmer, Michael; Scheschkewitz, David (Royal Society of Chemistry, 2018-08)

1,2,3-Trisilacyclopentadienes are obtained from the reactions of cyclotrisilene c-Si3R4 (R = iPr3C6H2) with phenyl and diphenyl acetylene, respectively. With 1,4-diethynyl benzene the crossconjugated bridging of two of the ...

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