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  • Cations and dications of heavier group 14 elements in low oxidation states 
    Swamy, V. S. V. S. N.; PAL, SHIV; KHAN, SHABANA; Sen, Sakya S. (Royal Society of Chemistry, 2015-06)
    Cations and dications of heavier group 14 elements in their low oxidation state have received widespread attention in recent years. The journey started with the isolation of a series of cations of the composition [(C5Me5)E:]+ ...
  • Facile access to a Ge(II) dication stabilized by isocyanides 
    Swamy, V. S. V. S. N.; Yadav, Sandeep; PAL, SHIV; Das, Tamal; Vanka, Kumar; Sen, Sakya S. (Royal Society of Chemistry, 2016-05)
    Herein, we introduce isocyanide as a ligand in main group chemistry and describe the facile isolation of a Ge(II) dication. The reaction of 2,6-dimethylphenylisocyanide with GeCl2 leads to the formation of a Ge(II) dication ...
  • C(sp3)–F, C(sp2)–F and C(sp3)–H bond activation at silicon(ii) centers 
    Swamy, V. S. V. S. N.; PARVIN, NASRINA; Raj, K. Vipin; Vanka, Kumar; Sen, Sakya S. (Royal Society of Chemistry, 2017-08)
    Silylene [PhC(NtBu)2SiN(SiMe3)2] (1) cleaves the C(sp3)–H and C–F bonds of acetophenone and 1,1,1-trifluoroacetophenone, respectively, under mild conditions. The reaction is initiated via a nucleophilic attack from the ...

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