UDAYA, HOSAHALLI S.; BASAVARAJAPPA, ASHOKKUMAR; GOPALAKRISHNA, TULLIMILLI Y.; ANAND, V. G.(Royal Society of Chemistry, 2022-12)
50π decathiophene expanded isophlorin adopts a unique [6+4] conformation and a near-planar conformation depending on the solvent of crystallization and undergoes a reversible two electron oxidation to yield the largest ...
MISHRA, VISHNU; UDAYA, HOSAHALLI S.; ANAND, V. G.(Royal Society of Chemistry, 2023-10)
Maximum confusion in porphyrinoids can be achieved by inter-linking heterocycles only through 2,4-connectivity. 20π confused porphycene and 30π expanded porphycene represent examples with the highest number of confused ...
UDAYA, HOSAHALLI S.; MISHRA, VISHNU; GOPALAKRISHNA, TULLIMILLI Y.; ANAND, V. G. (American Chemical Society, 2023-11)
Thiophene-based expanded porphyrinoids undergo a transition from a planar conformation to a twisted conformation upon a systematic increase in the number of thiophene units. Octaphyrin, with 40π electrons, displayed ...