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  • Reductive Cleavage of Carbon Monoxide by a Disilenide 
    MAJUMDAR, MOUMITA; Omlor, Isabell; Yildiz, Cem B.; Azizoglu, Akin; Huch, Volker; Scheschkewitz, David (Wiley, 2015-07)
    The complete reductive cleavage of the triple bond in carbon monoxide was achieved using a lithium disilenide at room temperature. The CC‐coupled product can be regarded as a silanone dimer with pending alkyne and silirene ...
  • NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity 
    Dhara, Debabrata; VIJAYAKANTH, THANGAVEL; Barman, Milan Kr.; Naik, Khevath Praveen Kumar; Chrysochos, Nicolas; Yildiz, Cem B.; BOOMISHANKAR, RAMAMOORTHY; Carola, Schulzke; Chandrasekhar, Vedapalli; Jana, Anukul (Royal Society of Chemistry, 2017-07)
    A facile, straightforward synthesis of N-heterocyclic carbene (NHC)-stabilized 1-hydrosilaimine starting from a silicon(IV)-precursor is reported. It has been employed for the addition of an O-H bond of water under ambient ...
  • Stabilization of the Elusive Antimony(I) Cation and Its Coordination Complexes with Transition Metals 
    KUMAR, VIKAS; Gonnade, Rajesh G.; Yildiz, Cem B.; MAJUMDAR, MOUMITA (Wiley, 2021-11)
    Upon stabilization by 5,6-bis(diisopropylphosphino)acenaphthene to form compound 1, the fugitive antimony (I) cation exhibited nucleophilic behavior towards coinage metals. Compound 1 was strategically synthesized at room ...
  • Intramolecular donor-stabilized tetra-coordinated germanium(iv) di-cations and their Lewis acidic properties 
    PEDDI, BALAKRISHNA; KHAN, SOUVIK; Gonnade, Rajesh G.; Yildiz, Cem B.; MAJUMDAR, MOUMITA (Royal Society of Chemistry, 2023-12)
    We report the first examples of intramolecular phosphine-stabilized tetra-coordinated germanium(iv) di-cationic compounds: [(L2Ge)-Ge-iPr][CF3SO3](2)3iPr and [(L2Ge)-Ge-Ph][CF3SO3](2)3Ph (L-iPr = 6-(diisopropylphosphanyl ...

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