The extreme significance of heavy hydrogen (D2) in medicinal, nuclear, and chemical sectors, despite its scarce natural abundance, underscores the vital imperative for inventing novel chemistries for its production. We ...

Herein, we report the synthesis and catalytic application of a new N,N′-dineopentyl-1,2-phenylenediamine-based bismuthenium cation (3). 3 has been synthesized via the treatment of chlorobismuthane LBiCl [L = 1,2-C6H4{N(CH2tBu)}2] ...

For N integer ≥1, K. Murty and D. Ramakrishnan defined the Nth Heisenberg curve, as the compactified quotient X′N of the upper half-plane by a certain non-congruence subgroup of the modular group. They ask whether the ...

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Quantum transport in nonequilibrium settings plays a fundamental role in understanding the properties of systems ranging from quantum devices to biological systems. Dephasing—a key aspect of out-of-equilibrium systems—arises ...

Plants or tissues can be regenerated through various pathways. Like animal regeneration, cell totipotency and pluripotency are the molecular basis of plant regeneration. Detailed systematic studies on Arabidopsis ...

This work reports that ligand engineering can modulate the triplet harvesting mechanism in iodide-bridged rhombic Cu2I2 complexes. Complex-1, with a smaller Cu–Cu distance, exhibits phosphorescence from 3(M+X)LCT and 3CC ...

Few synthetic ion transporters have been reported incorporating indole as the core moiety. We have developed a novel bisindole-based transporter capable of efficient transmembrane anion antiport. This system induced ...

The prevailing view about molecular catalysts is that the central metal ion is responsible for the reaction mechanism and selectivity, whereas the ligands mainly affect the reaction kinetics. Here, we question this paradigm ...

onic cocrystals with hydrogen bonding can form exciting materials with enhanced optical and electronic properties. We present a highly moisture-stable ammonium salt cocrystal [CH3C6H4CH(CH3)NH2][CH3C6H4CH(CH3)NH3][PF6] ...