dc.contributor.author |
SHAIKH, MOSEEN A. |
en_US |
dc.contributor.author |
UBALE, AKASH S. |
en_US |
dc.contributor.author |
GNANAPRAKASAM, BOOPATHY |
en_US |
dc.date.accessioned |
2021-09-27T07:06:51Z |
|
dc.date.available |
2021-09-27T07:06:51Z |
|
dc.date.issued |
2021-11 |
en_US |
dc.identifier.citation |
Advanced Synthesis & Catalysis, 363(21), 4876-4882. |
en_US |
dc.identifier.issn |
1615-4169 |
en_US |
dc.identifier.uri |
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6282 |
|
dc.identifier.uri |
https://doi.org/10.1002/adsc.202100793 |
en_US |
dc.description.abstract |
Indium-catalyzed sequential remote C−H functionalization (C-6 position) and C3-indolylation of peroxyoxindole using indole is described for the synthesis of terindolinone derivatives. Whereas, N-substituted 3-phenyl peroxyoxindole derivatives undergoes consecutive skeletal rearrangement to generate transient carbocation, which has been trapped with indole nucleophile to generate 2-(1H-indol-3-yl)-4-alkyl-benzo[b][1,4]oxazin-3(4H)-one derivatives. In contrast with Indium (III) Chloride, FeCl3 ⋅ 6H2O facilitates oxidative cleavage of the peroxyoxindole (Hock cleavage) and further reaction with indole to afford biologically important trisindoline derivatives. A plausible mechanism has been proposed for these reactions with experimental evidences. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Wiley |
en_US |
dc.subject |
Chemistry |
en_US |
dc.subject |
2021-SEP-WEEK3 |
en_US |
dc.subject |
TOC-SEP-2021 |
en_US |
dc.subject |
2021 |
en_US |
dc.title |
Indium Catalyzed Sequential Regioselective Remote C−H Indolylation and Rearrangement Reaction of Peroxyoxindole |
en_US |
dc.type |
Article |
en_US |
dc.contributor.department |
Dept. of Chemistry |
en_US |
dc.identifier.sourcetitle |
Advanced Synthesis & Catalysis |
en_US |
dc.publication.originofpublisher |
Foreign |
en_US |