Ru-MACHO-Catalyzed Direct Inter/Intramolecular Macrocyclization of Alcohols and Ketones

SUTAR, DASHRAT VISHAMBAR; GNANAPRAKASAM, BOOPATHY; JAMDADE, AKASH BANDU; BISHT, GIRISH SINGH

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dc.contributor.author	JAMDADE, AKASH BANDU	en_US
dc.contributor.author	SUTAR, DASHRAT VISHAMBAR	en_US
dc.contributor.author	BISHT, GIRISH SINGH	en_US
dc.contributor.author	GNANAPRAKASAM, BOOPATHY	en_US
dc.date.accessioned	2021-09-27T07:06:51Z
dc.date.available	2021-09-27T07:06:51Z
dc.date.issued	2021-10	en_US
dc.identifier.citation	Organic Letters, 23(19), 7386–7390.	en_US
dc.identifier.issn	1523-7060	en_US
dc.identifier.issn	1523-7052	en_US
dc.identifier.uri	https://doi.org/10.1021/acs.orglett.1c02569	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6283
dc.description.abstract	Herein we describe a new approach for end-to-end cyclization to construct macrocycles through the inter/intramolecular dehydrogenative coupling of alcohols and ketones in the presence of a Ru-MACHO catalyst. This method is highly atom economical and sustainable and can be used for many substrates. Additionally, this method results in the generation of only water as the byproduct. Moreover, in this approach, high dilution of the reactants is crucial for cyclization and high-yield macrocycle synthesis.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Chemistry	en_US
dc.subject	2021-SEP-WEEK3	en_US
dc.subject	TOC-SEP-2021	en_US
dc.subject	2021	en_US
dc.title	Ru-MACHO-Catalyzed Direct Inter/Intramolecular Macrocyclization of Alcohols and Ketones	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Organic Letters	en_US
dc.publication.originofpublisher	Foreign	en_US