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Access to transition metal complexes of phosphine-NHC based hybrid ligand

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dc.contributor.advisor KHAN, SHABANA en_US
dc.contributor.author RANI, POOJA en_US
dc.date.accessioned 2022-01-20T10:26:03Z
dc.date.available 2022-01-20T10:26:03Z
dc.date.issued 2021-12 en_US
dc.identifier.citation 37 en_US
dc.identifier.uri http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6531
dc.description.abstract C4-bound N-heterocyclic carbene (NHCs) referred to as ‘abnormal’ carbenes grabs considerable attention among the researchers as the zwitterionic form of C-4 bound carbenes are stronger sigma donor than classical C-2 bound carbenes. Moreover, the C-4 position of NHC ligands can be further utilized as an additional functionalization to develop the bimetallic and multimetallic architectures. Inspired by this concept, many researchers are actively working on development of homobimetallic and heterobimetallic NHC-based complexes which are significantly useful in tandem reactions. Donor ability act along with stable bond formation with transition metals (TM) forges them a brilliant ligand in coordination chemistry. Herein, C-4 bound phosphine NHC based transition metal complexes (IDIPP-PPh2)FeCl3, (IDIPPPPh2)NiCl2 , (IDIPP-PPh2)CoCl2, (IDIPP-PPh2)FeCl2, (IDIPP-PPh2)NiBr2, (IDIPPPPh2)FeBr2, (IDIPP-PPh2(S))CuCl, (IDIPP-PPh2(Se))CuCl and heterobimetallic complex (IDIPP-PPh2)PdCl2[CuCl] have been synthesized. NMR, HRMS investigations have been carried out for confirmation. The as-prepared complexes are highly stable at room temperature. Their catalytic activity can be explored further. en_US
dc.description.sponsorship Indian Institute of Science Education and Research, Pune en_US
dc.language.iso en en_US
dc.subject C-4 Substituted NHC ligands en_US
dc.title Access to transition metal complexes of phosphine-NHC based hybrid ligand en_US
dc.type Thesis en_US
dc.type.degree MS-exit en_US
dc.contributor.department Dept. of Chemistry en_US
dc.contributor.registration 20182009 en_US


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  • MS THESES [1703]
    Thesis submitted to IISER Pune in partial fulfilment of the requirements for the BS-MS Dual Degree Programme/MSc. Programme/MS-Exit Programme

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