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Reversible redox switching between local and global aromaticity for core-modified expanded carbaisophlorinoids

Reversible redox switching between local and global aromaticity for core-modified expanded carbaisophlorinoids

AMBHORE, MADAN D.; PANCHAL, SANTOSH P.; Mondal, Arpan; Konar, Sanjit; ANAND, V. G.
URI: https://doi.org/10.1039/D1OB02230J
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6745
Date: 2022-03


Abstract:

Two dithienothiophene based 28π antiaromatic macrocycles with benzene and azulene units and their effects on local and global (anti)aromaticity have been described. Experimental and computational studies confirmed the presence of weak paratropic and strong diatropic ring current effects in neutral and dicationic states, respectively.

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