Magnetism in bimetallic NiII-CoII coordination polymer

GUPTA, KRITI; Dadwal, Arun; Joy, Pattayil A.; BALLAV, NIRMALYA

dc.contributor.author	GUPTA, KRITI
dc.contributor.author	Dadwal, Arun
dc.contributor.author	Joy, Pattayil A.
dc.contributor.author	BALLAV, NIRMALYA
dc.date.accessioned	2022-06-22T09:19:20Z
dc.date.available	2022-06-22T09:19:20Z
dc.date.issued	2020-11
dc.identifier.citation	AIP Conference Proceedings, 2265(1), 030585.	en_US
dc.identifier.issn	0094-243X
dc.identifier.issn	1551-7616
dc.identifier.uri	https://aip.scitation.org/doi/abs/10.1063/5.0017747	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7141
dc.description.abstract	Co-BDC ([Co2(OH)2BDC], H2BDC = 1,4-benzenedicarboxylic acid) is known to possess metamagnetism originating from the antiparallel spins and high magneto crystalline anisotropy of Co(II).1 Herein, we have introduced a bimetallic concept by incorporating Ni(II) along with Co(II) in the same coordination polymer to modulate the magneto crystalline anisotropy in the lattice which in turn, affects the overall magnetic response of the coordination polymer. The Curie-Weiss equation fit suggested antiparallel arrangement of the spins (θ ≈ -62.5 K) of Ni(II) and Co(II) arranged in alternate fashion. The cusp in magnetization was observed at 7 K (Tc) with a significant coercive field of ∼750 Oe at 5 K.	en_US
dc.language.iso	en	en_US
dc.publisher	AIP Publishing	en_US
dc.subject	Chemistry	en_US
dc.subject	2020	en_US
dc.title	Magnetism in bimetallic NiII-CoII coordination polymer	en_US
dc.type	Conference Papers	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.doi	https://doi.org/10.1063/5.0017747	en_US
dc.publication.originofpublisher	Foreign	en_US