Dehydrogenative Intramolecular Macrolactonization of Dihydroxy Compounds Using Ru-MACHO Catalyst

dc.contributor.author	JAMDADE, AKASH BANDU	en_US
dc.contributor.author	SUTAR, DASHRAT VISHAMBAR	en_US
dc.contributor.author	GNANAPRAKASAM, BOOPATHY	en_US
dc.date.accessioned	2022-07-22T10:55:28Z
dc.date.available	2022-07-22T10:55:28Z
dc.date.issued	2022-06	en_US
dc.identifier.citation	Organic Letters, 24(24), 4394–4398.	en_US
dc.identifier.issn	1523-7052	en_US
dc.identifier.issn	1523-7060	en_US
dc.identifier.uri	https://doi.org/10.1021/acs.orglett.2c01617	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7249
dc.description.abstract	Herein, we have developed a new approach for the synthesis of 11 to 21-membered macrolactones via intramolecular dehydrogenative coupling of primary alcohols by using Ru-MACHO as a catalyst and Cs2CO3 as a base. This protocol generated 11–21-ring-sized macrocycles (26 derivatives), free from an external oxidant or an additive, eliminating stoichiometric reagents and producing only hydrogen as a byproduct.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Alcohols	en_US
dc.subject	Catalysts	en_US
dc.subject	Chemical reactions	en_US
dc.subject	Hydrocarbons	en_US
dc.subject	Hydrogen	en_US
dc.subject	2022-JUL-WEEK2	en_US
dc.subject	TOC-JUL-2022	en_US
dc.subject	2022	en_US
dc.title	Dehydrogenative Intramolecular Macrolactonization of Dihydroxy Compounds Using Ru-MACHO Catalyst	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Organic Letters	en_US
dc.publication.originofpublisher	Foreign	en_US