Tailoring diradicaloid properties of expanded isophlorinoids with systematic core-modification

AMBHORE, MADAN D.; SHUKLA, PRAGATI; Gonnade, Rajesh G.; ANAND, V. G.

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dc.contributor.author	AMBHORE, MADAN D.	en_US
dc.contributor.author	SHUKLA, PRAGATI	en_US
dc.contributor.author	Gonnade, Rajesh G.	en_US
dc.contributor.author	ANAND, V. G.	en_US
dc.date.accessioned	2022-07-29T09:06:04Z
dc.date.available	2022-07-29T09:06:04Z
dc.date.issued	2022-08	en_US
dc.identifier.citation	Chemical Communications, 58(64), 8946-8949.	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	https://doi.org/10.1039/D2CC02970G	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7287
dc.description.abstract	Herein, we describe the synthesis, structural diversity and diradicaloid characteristics of 38π core-modified aromatic expanded isophlorins with eight heterocyclic rings. The diradicaloid character of expanded isophlorinoid macrocycles was engineered by systematic structural modification. Depending on the nature of the link between the heteroatoms, they adopt planar and non-planar conformations. This large structural variation with a significant difference in the extent of aromaticity is correlated with the magnitude of their respective diradical character.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Porphyrin	en_US
dc.subject	2022-JUL-WEEK4	en_US
dc.subject	TOC-JUL-2022	en_US
dc.subject	2022	en_US
dc.title	Tailoring diradicaloid properties of expanded isophlorinoids with systematic core-modification	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US