Donor free stibenium cation as an efficient cyanosilylation catalyst

KHAN, SHABANA; GOTHE, PRACHI; Das, Shubhajit; SEN, NILANJANA; Tothadi, Srinu; Pati, Swapan K.; Sarkar, Pallavi

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dc.contributor.author	SEN, NILANJANA	en_US
dc.contributor.author	GOTHE, PRACHI	en_US
dc.contributor.author	Sarkar, Pallavi	en_US
dc.contributor.author	Das, Shubhajit	en_US
dc.contributor.author	Tothadi, Srinu	en_US
dc.contributor.author	Pati, Swapan K.	en_US
dc.contributor.author	KHAN, SHABANA	en_US
dc.date.accessioned	2022-09-13T10:42:14Z
dc.date.available	2022-09-13T10:42:14Z
dc.date.issued	2022-09	en_US
dc.identifier.citation	Chemical Communications, 58(74), 10380-10383.	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	https://doi.org/10.1039/D2CC03158B	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7355
dc.description.abstract	The synthesis of novel stibenium cations and their catalytic application in cyanosilylation of carbonyl compounds have been described. Treatment of chlorostibine L1SbCl [L1 = 1,2-C6H4{N(CH2tBu)}2] (2) with 1 equiv. of AgOTf and AgSbF6 resulted in the formation of donor free L1SbOTf (3) and [L1Sb]+[SbF6]− (4), respectively. Among these three compounds, 4 exhibits excellent catalytic activity towards the cyanosilylation of aldehydes and ketones.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Pnictogenium Cations	en_US
dc.subject	Lewis Acidity	en_US
dc.subject	Hydroboration	en_US
dc.subject	Activation	en_US
dc.subject	Hydrosilylation	en_US
dc.subject	Chemistry	en_US
dc.subject	Germylene	en_US
dc.subject	Antimony	en_US
dc.subject	Complex	en_US
dc.subject	2022-SEP-WEEK1	en_US
dc.subject	TOC-SEP-2022	en_US
dc.subject	2022	en_US
dc.title	Donor free stibenium cation as an efficient cyanosilylation catalyst	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US