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Silylene Supported Ni Complex and Its Catalytic Application in C-N Coupling Reactions

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dc.contributor.advisor KHAN, SHABANA
dc.contributor.author MEENA, RAKESH
dc.date.accessioned 2022-12-13T08:07:13Z
dc.date.available 2022-12-13T08:07:13Z
dc.date.issued 2022-12
dc.identifier.citation 61 en_US
dc.identifier.uri http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7499
dc.description.abstract The chemistry of N-heterocyclic silylenes (NHSis) [a higher analogue of NHC], is one of the hottest research topics in current low-valent organometallic chemistry. In this work, a hybrid N-heterocyclic silylene (NHSi) and phosphine-based compound was developed and used as a ligand in transition metal-catalyzed homogeneous catalysis. We will be discussing the development and electronic as well as steric properties of silylenes especially NHSi ligands to achieve the potential catalyst for transition metal-catalyzed organic transformation. The electronic and steric properties of the newly synthesized silylene- and phosphine-based hybrid ligand are described. Further, the application of the ligand-supported NiII complex in the C-N coupling reactions as potent catalyst is described. Next section will cover the synthesis and characterization of the NHSi and phosphine-based ligand and its NiII metal complex. en_US
dc.language.iso en en_US
dc.subject Silylene en_US
dc.subject Ligand en_US
dc.subject Transition metal complex en_US
dc.subject Homogeneous catalysis en_US
dc.title Silylene Supported Ni Complex and Its Catalytic Application in C-N Coupling Reactions en_US
dc.type Thesis en_US
dc.description.embargo no embargo en_US
dc.type.degree BS-MS en_US
dc.contributor.department Dept. of Chemistry en_US
dc.contributor.registration 20161021 en_US


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  • MS THESES [1705]
    Thesis submitted to IISER Pune in partial fulfilment of the requirements for the BS-MS Dual Degree Programme/MSc. Programme/MS-Exit Programme

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