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Transient Directing Group Enabled C3-(sp2)−H Alkenylation of Five Membered Heterocyclic Aldehydes: An Access to Mechanochromic Luminogen

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dc.contributor.author SHAIKH, JAVED Y. en_US
dc.contributor.author BHOWMICK, ANINDITA en_US
dc.contributor.author CHATTERJEE, ABHIJIT en_US
dc.contributor.author THOMBARE, NITIN A. en_US
dc.contributor.author BHAT, RAMAKRISHNA G. en_US
dc.date.accessioned 2023-08-11T07:21:49Z
dc.date.available 2023-08-11T07:21:49Z
dc.date.issued 2023-09 en_US
dc.identifier.citation Advanced Synthesis & Catalysis, 365(17), 2922-2928. en_US
dc.identifier.issn 1615-4150 en_US
dc.identifier.issn 1615-4169  en_US
dc.identifier.uri https://doi.org/10.1002/adsc.202300528 en_US
dc.identifier.uri http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/8132
dc.description.abstract The palladium (II) catalyzed direct C3-(sp2)−H alkenylation of five membered heterocyclic aldehydes has been developed using 3-aminobutanoic acid as a catalytic transient directing group. A wide range of heterocyclic aldehydes reacted with various acrylates to afford highly site-selective C3-alkenylated products. This method features an exclusive E-selective alkenylation at the C3-position of heterocyclic aldehydes with a broad substrate scope. The protocol also proved to be useful to construct the mechanochromic luminogen. en_US
dc.language.iso en en_US
dc.publisher Wiley en_US
dc.subject Organic chemistry en_US
dc.subject Inorganic chemistry en_US
dc.subject Organometallic chemistry en_US
dc.subject Green chemistry en_US
dc.subject Homogeneous catalysis en_US
dc.subject Heterogeneous catalysis en_US
dc.subject Organocatalysis en_US
dc.subject Enzyme catalysis en_US
dc.subject Asymmetric catalysis en_US
dc.subject Multiphase catalysis en_US
dc.subject Organic synthesis en_US
dc.subject Asymmetric synthesis en_US
dc.subject Synthetic methods en_US
dc.subject Supported catalysts en_US
dc.subject Ligand design en_US
dc.title Transient Directing Group Enabled C3-(sp2)−H Alkenylation of Five Membered Heterocyclic Aldehydes: An Access to Mechanochromic Luminogen en_US
dc.type Article en_US
dc.contributor.department Dept. of Chemistry en_US
dc.identifier.sourcetitle Advanced Synthesis & Catalysis en_US
dc.publication.originofpublisher Foreign en_US


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