Redox Assisted Reversible Aromaticity Transition Between 30π Hückel and 28π Möbius Dication of a Core-Modified Isophlorinoid

AMBHORE, MADAN D.; SHUKLA, PRAGATI; ANAND, V. G.

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dc.contributor.author	SHUKLA, PRAGATI	en_US
dc.contributor.author	AMBHORE, MADAN D.	en_US
dc.contributor.author	ANAND, V. G.	en_US
dc.date.accessioned	2024-02-05T07:27:17Z
dc.date.available	2024-02-05T07:27:17Z
dc.date.issued	2023-05	en_US
dc.identifier.citation	Chemistry – A European Journal, 29(25).	en_US
dc.identifier.issn	0947-6539	en_US
dc.identifier.issn	1521-3765	en_US
dc.identifier.uri	https://doi.org/10.1002/chem.202203327	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/8458
dc.description.abstract	The electronic properties of a hexaphyrin was fine-tuned via core-modification leading to the formation of a Hückel aromatic 30π hexaphyrin which incorporates two pyrrole and four furan rings in the π-conjugated pathway. This Hückel aromatic hexaphyrin modified its conformation upon two-electron ring oxidation either with triflic acid or Meerwein salt [Et3O]+[SbCl6]− to yield 28π Möbius aromatic dication species. Reversible aromatic transition was established by spectroscopic techniques and further supported by quantum chemical calculations.	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley	en_US
dc.subject	Annulenes	en_US
dc.subject	Aromaticity	en_US
dc.subject	Heterocycles	en_US
dc.subject	Porphyrinoids	en_US
dc.subject	Spectroelectrochemistry	en_US
dc.subject	2023	en_US
dc.title	Redox Assisted Reversible Aromaticity Transition Between 30π Hückel and 28π Möbius Dication of a Core-Modified Isophlorinoid	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemistry – A European Journal	en_US
dc.publication.originofpublisher	Foreign	en_US