Synthesis and catalytic application of a donor-free bismuthenium cation

dc.contributor.author	SEN, NILANJANA	en_US
dc.contributor.author	Sarkar, Pallavi	en_US
dc.contributor.author	MEENA, YADRAM	en_US
dc.contributor.author	Tothadi, Srinu	en_US
dc.contributor.author	Pati, Swapan K.	en_US
dc.contributor.author	KHAN, SHABANA	en_US
dc.date.accessioned	2024-07-01T03:59:13Z
dc.date.available	2024-07-01T03:59:13Z
dc.date.issued	2024-06	en_US
dc.identifier.citation	Chemical Communications	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	https://doi.org/10.1039/D4CC01805B	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/9000
dc.description.abstract	Herein, we report the synthesis and catalytic application of a new N,N′-dineopentyl-1,2-phenylenediamine-based bismuthenium cation (3). 3 has been synthesized via the treatment of chlorobismuthane LBiCl [L = 1,2-C6H4{N(CH2tBu)}2] (2) with AgSbF6, and was further used as a robust catalyst for the cyanosilylation of ketones under mild reaction conditions. Experimental studies and DFT calculations were performed to understand the mechanistic pathway.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Cyanosilylation	en_US
dc.subject	2024	en_US
dc.subject	2024-JUN-WEEK3	en_US
dc.subject	TOC-JUN-2024	en_US
dc.title	Synthesis and catalytic application of a donor-free bismuthenium cation	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US