Open shell (4n + 2)π and closed shell 4nπ planar core-modified decaphyrins

dc.contributor.author	SHUKLA, PRAGATI	en_US
dc.contributor.author	AMBHORE, MADAN D.	en_US
dc.contributor.author	ANAND, V. G.	en_US
dc.date.accessioned	2025-04-15T06:43:30Z
dc.date.available	2025-04-15T06:43:30Z
dc.date.issued	2024-04	en_US
dc.identifier.citation	Chemical Science, 15(16), 6022-6027.	en_US
dc.identifier.issn	2041-6520	en_US
dc.identifier.issn	2041-6539	en_US
dc.identifier.uri	https://doi.org/10.1039/D3SC05251F	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/9459
dc.description.abstract	Planar 44π and 46π core-modified decaphyrins with ten thiophene units have been synthesized from short thiophene oligomers. They have been structurally characterized by single crystal X-ray diffraction with further support from spectroscopic analysis and quantum chemical calculations. Our analysis revealed diradicaloid characteristics for 46π species in contrast to the closed shell property of the 44π congener. Further, 44π and 46π undergo reversible two-electron chemical oxidation, as observed by spectro-electrochemical measurements.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Expanded Porphyrin	en_US
dc.subject	2024	en_US
dc.title	Open shell (4n + 2)π and closed shell 4nπ planar core-modified decaphyrins	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Science	en_US
dc.publication.originofpublisher	Foreign	en_US