Total Synthesis of Conjugation-Ready Hyperbranched Pentasaccharide of Clavibacter phaseoli VKM Ac-2641T by [Au]/[Ag] Catalysis

DAS, PRATIM KUMAR; HOTHA, SRINIVAS

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dc.contributor.author	DAS, PRATIM KUMAR	en_US
dc.contributor.author	HOTHA, SRINIVAS	en_US
dc.date.accessioned	2025-04-15T06:48:30Z
dc.date.available	2025-04-15T06:48:30Z
dc.date.issued	2024-07	en_US
dc.identifier.citation	Organic Letters, 26(31), 6709–6713.	en_US
dc.identifier.issn	1523-7060	en_US
dc.identifier.issn	1523-7052	en_US
dc.identifier.uri	https://doi.org/10.1021/acs.orglett.4c02386	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/9487
dc.description.abstract	Infections by Clavibacter spp. cause an economic burden to farmers. The components present in the cell wall glycopolymers (CWGs) are important for studying the host–pathogen interactions, colonization, and infection. A pentasaccharide containing a hyperbranched Ribf-, Galf-, and Manp- has recently been identified. Herein, we describe the first total synthesis of the conjugation-ready hyperbranched pentasaccharide of C. phaseoli VKM Ac-2641T using the [Au]/[Ag]-catalyzed glycosidation chemistry of ethynylcyclohexyl carbonate glycosyl donors. The pentasaccharide was synthesized in a highly convergent fashion from readily accessible monosaccharide building blocks.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Carbon	en_US
dc.subject	Ethers	en_US
dc.subject	Infectious diseases	en_US
dc.subject	Inorganic carbon compounds	en_US
dc.subject	Plant derived food	en_US
dc.subject	2024	en_US
dc.title	Total Synthesis of Conjugation-Ready Hyperbranched Pentasaccharide of Clavibacter phaseoli VKM Ac-2641T by [Au]/[Ag] Catalysis	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Organic Letters,	en_US
dc.publication.originofpublisher	Foreign	en_US